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Thursday, December 2, 2010

Type 1 Superconductors And a Periodic Chart Comparison



The Type 1 category of superconductors is mainly comprised of metals and metalloids that show some conductivity at room temperature. They require incredible cold to slow down molecular vibrations sufficiently to facilitate unimpeded electron flow in accordance with what is known as BCS theory. BCS theory suggests that electrons team up in "Cooper pairs" in order to help each other overcome molecular obstacles - much like race cars on a track drafting each other in order to go faster. Scientists call this process phonon-mediated coupling because of the sound packets generated by the flexing of the crystal lattice.
      Type 1 superconductors - characterized as the "soft" superconductors - were discovered first and require the coldest temperatures to become superconductive. They exhibit a very sharp transition to a superconducting state (see above graph) and "perfect" diamagnetism - the ability to repel a magnetic field completely. Below is a list of known Type 1 superconductors along with the critical transition temperature (known as Tc) below which each superconducts. The 3rd column gives the lattice structure of the solid that produced the noted Tc. Surprisingly, copper, silver and gold, three of the best metallic conductors, do not rank among the superconductive elements. Why is this ?


Lead (Pb)
Lanthanum (La)
Tantalum (Ta)
Mercury (Hg)
Tin (Sn)
Indium (In)
Palladium (Pd)*
Chromium (Cr)*
Thallium (Tl)
Rhenium (Re)
Protactinium (Pa)
Thorium (Th)
Aluminum (Al)
Gallium (Ga)
Molybdenum (Mo)
Zinc (Zn)
Osmium (Os)
Zirconium (Zr)
Americium (Am)
Cadmium (Cd)
Ruthenium (Ru)
Titanium (Ti)
Uranium (U)
Hafnium (Hf)
Iridium (Ir)
Beryllium (Be)
Tungsten (W)
Platinum (Pt)*
Lithium (Li)
Rhodium (Rh)

7.196 K
4.88 K
4.47 K
4.15 K 
3.72 K
3.41 K
3.3 K
3 K
2.38 K
1.697 K
1.40 K
1.38 K
1.175 K
1.083 K
0.915 K
0.85 K
0.66 K
0.61 K
0.60 K
0.517 K
0.49 K
0.40 K
0.20 K
0.128 K
0.1125 K
0.023 K  (SRM 768)
0.0154 K
0.0019 K
0.0004 K
0.000325 K

FCC
HEX
BCC
RHL
TET
TET
(see note 1)
(see note 1)
HEX
HEX
TET
FCC
FCC
ORC
BCC
HEX
HEX
HEX
HEX
HEX
HEX
HEX
ORC
HEX
FCC
HEX
BCC 

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